Electric Literature of 460-37-7, As an important bridge between the micro and macro material world, chemistry is one of the main methods and means for humans to understand and transform the material world. 460-37-7, Name is 1,1,1-Trifluoro-3-iodopropane, SMILES is ICCC(F)(F)F, belongs to iodides-buliding-blocks compound. In a article, author is EVANS, GJ, introduce new discover of the category.
THE VOLATILIZATION OF IODINE SPECIES OVER DILUTE IODIDE SOLUTIONS
The volatility of iodine above dilute CsI solutions has been investigated experimentally. The partitioning of iodine between air and solutions prepared with iodide was found to increase with decreasing pH and iodide concentration. Aqueous to gaseous partition coefficients ranging from 3 x 10(3) to 10(7) were observed indicating that only a very small fraction of the iodide was oxidized to volatile forms. It was concluded that under these very dilute conditions, the rate of iodide oxidation was proportional to the square root of the iodide concentration; the rate also depended on pH under acidic conditions but not under basic conditions.
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