Hong, Sungjun; Huber, Stefan M.; Gagliardi, Laura; Cramer, Christopher C.; Tolman, William B. published an article about the compound: Mesitylcopper(I)( cas:75732-01-3,SMILESS:[Cu]C1=C(C)C=C(C)C=C1C ).Recommanded Product: 75732-01-3. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:75732-01-3) through the article.
Cu(I)-α-ketocarboxylate complexes with aryl substituted iminoethylpyridines were prepared and shown to exhibit variable coordination modes of the α-ketocarboxylate ligand. Reaction with O2 induces decarboxylation of the α-ketocarboxylate, and the derived Cu-O intermediate(s) was intercepted, resulting in hydroxylation of an arene substituent on the supporting N-donor ligand. Theor. calculations provided intriguing mechanistic notions for the process, notably implicating hydroxylation pathways that involve novel [CuI-OOC(O)R] and [CuII-O-• ↔ CuIII:O2-]+ species.
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Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com