Lu, Panting; Chen, Wenxing; Lu, Wangyang published an article in 2021. The article was titled 《Solar photothermal catalytic effect promotes carbonylation reaction based on palladium doped g-C3N4 catalyst》, and you may find the article in Materials Research Bulletin.Category: iodides-buliding-blocks The information in the text is summarized as follows:
Palladium catalyzed carbonylation reaction is used as an effective method in the industrial to prepare carbonyl-containing compounds Besides, the complex ligands are needed to improve the yields and selectivity of reactions, which will increase the cost for production Thus, it is very meaningful to build a simple and efficient catalytic system. Here, the graphitic carbon nitride (g-C3N4) nanosheets (ECN) doped with palladium metal (Pd/ECN) were prepared by microwave-assisted deposition method. The results indicated that the yield of Me benzoate was 77% based on Pd/ECN under the light irradiation with a wavelength of ≥ 400 nm, which was higher than that of the homogeneous catalysts and heterogeneous catalysts commonly used in commercialization such as palladium on activated charcoal (Pd/C) and palladium chloride (PdCl2). In the part of experimental materials, we found many familiar compounds, such as 1-Chloro-3-iodobenzene(cas: 625-99-0Category: iodides-buliding-blocks)
1-Chloro-3-iodobenzene(cas: 625-99-0) belongs to organic iodides. The carbon-iodine bond is weaker than other carbon-halogen bonds due to the poor electronegative nature of the iodine atom. Category: iodides-buliding-blocks Organic iodides can be alkyl, alkenyl, or alkynyl, and all of them are very reactive toward with many kinds of nucleophiles.
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com