Whitaker, R. D.’s team published research in Journal of Inorganic and Nuclear Chemistry in 24 | CAS: 6443-90-9

Journal of Inorganic and Nuclear Chemistry published new progress about 6443-90-9. 6443-90-9 belongs to iodides-buliding-blocks, auxiliary class Pyridines, name is Pyridine Iodochloride complex, and the molecular formula is C40H35N7O8, Application of Pyridine Iodochloride complex.

Whitaker, R. D. published the artcileIodine monochloride and iodine trichloride systems involving pyridine and quinoline, Application of Pyridine Iodochloride complex, the publication is Journal of Inorganic and Nuclear Chemistry (1962), 285-9, database is CAplus.

Spectrophotometric studies indicate that only addition compounds with 1:1 stoichiometries are present in significant concentrations in CCl4 solutions of ICl or ICl, with heterocyclic amines. However, thermal studies reveal that in the solid state, in addition to the expected 1:1 type compounds, the system ICl4-pyridine forms C5H6N.2ICl3 (m.p. 140°) and ICl3.2C5H5N (m.p. 69° incongruent) and the system ICl2-quinoline forms ICl2.2C9H7N (m.p. 81°). The system ICl-quinoline forms only the 1:1 type compound, and a reinvestigation of part of the system ICl-pyridine confirmed the absence of a compound with a mole ratio of 1: 2 of ICl to pyridine.

Journal of Inorganic and Nuclear Chemistry published new progress about 6443-90-9. 6443-90-9 belongs to iodides-buliding-blocks, auxiliary class Pyridines, name is Pyridine Iodochloride complex, and the molecular formula is C40H35N7O8, Application of Pyridine Iodochloride complex.

Referemce:
https://en.wikipedia.org/wiki/Iodide,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com