The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: (2S)-(+)-3-Chloropropane-1,2-diol( cas:60827-45-4 ) is researched.SDS of cas: 60827-45-4.Jones, Haydn F. published the article 《Stereospecific synthesis of R- and S-3-chloropropan-1,2-diol》 about this compound( cas:60827-45-4 ) in Chemistry & Industry (London, United Kingdom). Keywords: chloropropandiol stereospecific preparation; propanediol chloro stereospecific preparation; glycoside synthon chloropropanediol. Let’s learn more about this compound (cas:60827-45-4).
S-ClCH2CH(OH)CH2OH (S-I) was prepared from Me 6-chloro-6-deoxy-α-D-glucopyranoside by sequential oxidative ring cleavage, reduction and hydrolysis. R-I was similarly prepared from Me 5-chloro-5-deoxy-α-L-arabinofuranoside, which was obtained from Me 2,3-di-O-benzoyl-5-O-(p-tolylsulfonyl)-α-L-arabinofuranoside by chlorination and then deesterification.
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Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com