《Green and Efficient Liquid-Phase Exfoliation of BiI3 Nanosheets for Catalytic Carbon-Carbon Cross-Coupling Reactions》 was published in ACS Sustainable Chemistry & Engineering in 2020. These research results belong to Wang, Huiyong; Song, Tao; Su, Xin; Li, Zhiyong; Wang, Jianji. Quality Control of 4-Iodobenzoic acid The article mentions the following:
BiI3 nanosheet dispersions were prepared by ultrasound-mediated exfoliation of BiI3 in the green solvents Me salicylate, triacetin, di-Et phthalate, Et benzoate, or in mixtures of the solvents. BiI3 nanosheets were formed in up to 30% yields and as dispersions containing up to 1.56 mg/mL of BiI3; the thickness of the BiI3 nanosheets is 5-10 nm and their lateral dimensions are around 1μm. Solvent-cosolvent interactions in the mixed solvents are a critical factor in the liquid-phase exfoliation. The BiI3 nanosheets were used as a catalyst for the Suzuki coupling of aryl iodides with phenylboronic acid mediated by TMEDA and KOH in THF to yield 4-substituted biphenyls in 75-91% yields. The experimental part of the paper was very detailed, including the reaction process of 4-Iodobenzoic acid(cas: 619-58-9Quality Control of 4-Iodobenzoic acid)
4-Iodobenzoic acid(cas: 619-58-9) belongs to organic iodides. Organic iodides are used in veterinary products (Organic Iodide Powder) as a nutritional source of iodine.Quality Control of 4-Iodobenzoic acid In the chemical industry, alkyl iodides serve as excellent alkylating agents and, specifically, methyl iodide is used as a methylating agent in the synthesis of various pharmaceutical drugs.
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com