Reference of 1-Chloro-3-iodobenzeneIn 2022 ,《Electrochemical Synthesis of Sulfonyl Fluorides with Triethylamine Hydrofluoride》 was published in Chinese Journal of Chemistry. The article was written by Zhang, Lei; Cheng, Xu; Zhou, Qi-Lin. The article contains the following contents:
Hydrofluoride is an industry-preferred fluoride source, and finds extensively application to manufacture diverse fluoro chems. The Et3N-3HF complex is a liquid HF with improve safety. In this work, electrochem. synthesis of a series of sulfonyl fluoride with Et3N-3HF as fluoride source was reported. The sulfinic salt is a smell-less, non-volatile, and air-stable sulfur source in this reaction. With the combination of Et3N-3HF and aryl/alkyl sulfinic salt, the sulfonyl fluorides are achieved without the use of external oxidant. In addition, further advantage in a tandem reaction involving Pd-catalyzed C-S cross-coupling and formation of S-F bond was demonstrated. A variety of functional groups including amino acids, heterocycles, halides are well tolerated. The experimental process involved the reaction of 1-Chloro-3-iodobenzene(cas: 625-99-0Reference of 1-Chloro-3-iodobenzene)
1-Chloro-3-iodobenzene(cas: 625-99-0) belongs to organic iodides. Generally organic iodides can be divided into two classes of alkyl iodides and aryl iodides. Typical reactions of alkyl iodides include nucleophilic substitution, elimination, reduction, and the formation of organometallics.Reference of 1-Chloro-3-iodobenzene
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com