Kuttler, Andrew’s team published research in Heteroatom Chemistry in 24 | CAS: 165534-79-2

Heteroatom Chemistry published new progress about 165534-79-2. 165534-79-2 belongs to iodides-buliding-blocks, auxiliary class Iodide,Benzene,Ester, name is Dimethyl 2-iodoterephthalate, and the molecular formula is C10H9IO4, Product Details of C10H9IO4.

Kuttler, Andrew published the artcileStructure, Theoretical Studies, and Coupling Reactions of Some New Cyclic Boronic Esters, Product Details of C10H9IO4, the publication is Heteroatom Chemistry (2013), 24(5), 361-371, database is CAplus.

The present report describes the x-ray structural and theor. studies of some new pinacolboronate esters, and it also outlines the use of the target structures in Suzuki coupling reactions to produce new aromatic or heteroaromatic esters and amides. X-ray structural anal. of the studied compounds revealed that the pinacolborane ring’s position with respect to the benzene ring varies, depending on the particular environment. An ortho-positioned carboxylic ester (Me ester) causes a nearly perpendicular orientation of the pinacolborane unit with respect to the benzene ring, whereas an ortho-positioned amide (N,N-dimethylamide) causes the pinacolborane unit to orient itself nearly coplanar. A plausible explanation was provided, based on both steric and electronic factors. © 2013 Wiley Periodicals, Inc. Heteroatom Chem.

Heteroatom Chemistry published new progress about 165534-79-2. 165534-79-2 belongs to iodides-buliding-blocks, auxiliary class Iodide,Benzene,Ester, name is Dimethyl 2-iodoterephthalate, and the molecular formula is C10H9IO4, Product Details of C10H9IO4.

Referemce:
https://en.wikipedia.org/wiki/Iodide,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com