Szczesniak, Piotr published the artcilePhoto-Fries-type rearrangement of cyclic enamides. An efficient route to structurally diverse five-membered enaminones, Synthetic Route of 638-45-9, the publication is Chemical Communications (Cambridge, United Kingdom) (2022), 58(12), 1898-1901, database is CAplus and MEDLINE.
A simple, efficient and user-friendly protocol for the preparation of structurally diverse enaminones e.g., I from enamides e.g., II has been developed. The strategy is based on a photo-induced intramol. Fries-type rearrangement. The photochem. transformation proceeds under mild reaction conditions, applies to a broad substrate range, is highly economic, and limits the amount of waste produced. The proposed methodol. was used as a key step in the synthesis of dihydrojasmone an important fragrance compound
Chemical Communications (Cambridge, United Kingdom) published new progress about 638-45-9. 638-45-9 belongs to iodides-buliding-blocks, auxiliary class Iodide,Aliphatic hydrocarbon chain, name is 1-Iodohexane, and the molecular formula is C8H17Br, Synthetic Route of 638-45-9.
Referemce:
https://en.wikipedia.org/wiki/Iodide,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com