TosMIC and its derivatives as versatile sulfonylating agents for the synthesis of p-toluenesulfonylarenes from aryl halides and arylboronic acids was written by Ravi Kumar, G.;Ramesh, B.;Banik, Swarnayu;Subba Reddy, B. V.. And the article was included in Tetrahedron in 2020.HPLC of Formula: 5460-32-2 This article mentions the following:
An efficient copper(II) catalyzed sulfonyation of aryl halides had been achieved using TosMIC (p-toluenesulfonylmethyl isocyanide) as a sulfonylating agent. This newly developed sulfonylation approach provided an easy access for the synthesis of diaryl sulfones I [Ar = Ph, 4-MeOC6H4, 2-pyridyl, etc.] from aryl bromides, iodides and boronic acids with TosMIC under neutral conditions. This method was useful for the sulfonylation of aryl boronic acids under similar conditions. This was the first report on the sulfonylation of aryl bromides, iodides and boronic acids using TosMIC. In the experiment, the researchers used many compounds, for example, 4-Iodo-1,2-dimethoxybenzene (cas: 5460-32-2HPLC of Formula: 5460-32-2).
4-Iodo-1,2-dimethoxybenzene (cas: 5460-32-2) belongs to iodide derivatives. Organic iodides can be alkyl, alkenyl, or alkynyl, and all of them are very reactive toward with many kinds of nucleophiles. Polyiodoorganic compounds are sometimes employed as X-ray contrast agents, in fluoroscopy, a type of medical imaging. This application exploits the X-ray absorbing ability of the heavy iodine nucleus.HPLC of Formula: 5460-32-2
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com