Downstream Synthetic Route Of 75732-01-3

I hope my short article helps more people learn about this compound(Mesitylcopper(I))Electric Literature of C9H11Cu. Apart from the compound(75732-01-3), you can read my other articles to know other related compounds.

In general, if the atoms that make up the ring contain heteroatoms, such rings become heterocycles, and organic compounds containing heterocycles are called heterocyclic compounds. An article called Copper/α-Ketocarboxylate Chemistry With Supporting Peralkylated Diamines: Reactivity of Copper(I) Complexes and Dicopper-Oxygen Intermediates, published in 2010-04-05, which mentions a compound: 75732-01-3, Name is Mesitylcopper(I), Molecular C9H11Cu, Electric Literature of C9H11Cu.

To further understand Cu-promoted oxidation reactions, the Cu(I) complexes LCuX (L = N,N’-di-tert-butyl-N,N’-dimethylethylenediamine; X = benzoylformate (BF) or p-nitro-benzoylformate) were synthesized, fully characterized by x-ray crystallog. and spectroscopy in solution, and their reactivity with O2 at -80° examined Oxidative decarboxylation of the α-ketocarboxylate ligand was observed, but only to a significant extent when cyclohexene, cyclooctene, or MeCN was present. Spectroscopic and conductivity data are consistent with mechanistic postulates involving displacement of the α-ketocarboxylate by the additives to a small extent, followed by oxygenation of the LCu(I) moiety to yield Cu-O species that subsequently induce decarboxylation. To test these hypotheses, spectroscopic and kinetic studies of the reactions of Bu4NBF with preformed μ-η2:η2-peroxodicopper(II) and/or bis(μ-oxo)dicopper(III) complexes supported by L or N,N,N’,N’-tetramethylpropylenediamine were performed. In an illustration of a new mode of reactivity for such dicopper-O cores, decarboxylation of the added α-ketocarboxylate was observed and the intermediacy of a carboxylate-bridged μ-η2:η2-peroxodicopper(II) complex was implicated.

I hope my short article helps more people learn about this compound(Mesitylcopper(I))Electric Literature of C9H11Cu. Apart from the compound(75732-01-3), you can read my other articles to know other related compounds.

Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com