The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: 2-Methylglutaronitrile(SMILESS: N#CC(C)CCC#N,cas:4553-62-2) is researched.Synthetic Route of C34H18F16IrN4P. The article 《Influence of the medium on hydrogenation of 2-methylglutaronitrile. Selective access to 2-methylpentane diamine or β-picoline after dehydrogenation》 in relation to this compound, is published in Chemical Industries (Dekker). Let’s take a look at the latest research on this compound (cas:4553-62-2).
A conference. The 2-methylglutaronitrile (I) is obtained as a byproduct of the important adiponitrile production It, nevertheless, gives rise to interesting chem. transformations. In particular, its hydrogenation can produce 2-methylpentanediamine, a substitute for hexamethylenediamine in polyamide or polyurethane compounds The 3-methylpiperidine, also produced by hydrogenation of I, can be an interesting intermediate for β-picoline production involved in the synthesis of PP vitamin. Using Raney nickel as the catalyst, hydrogenation reactions were performed in various liquid phase compositions 2-Methylpentanediamine was obtained very selectively. The reaction product can be used itself as solvent. Addition of dry ammonia in ethanol in the place of isopropanol / KOH or NaOH medium leads to a mixture of 2-methylpentanediamine, 3-methylpiperidine and some heavy byproducts. This mixture can be cyclized and dehydrogenated to β-picoline (3-methylpyridine) on a special and very efficient Pd/SiO2 catalyst. The two processes have been patented by Rhone-Poulenc.
Here is just a brief introduction to this compound(4553-62-2)HPLC of Formula: 4553-62-2, more information about the compound(2-Methylglutaronitrile) is in the article, you can click the link below.
Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com