So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Chikkade, Prasanna Kumara; Shimizu, Yohei; Kanai, Motomu researched the compound: Mesitylcopper(I)( cas:75732-01-3 ).Recommanded Product: Mesitylcopper(I).They published the article 《Catalytic enantioselective synthesis of 2-(2-hydroxyethyl)indole scaffolds via consecutive intramolecular amido-cupration of allenes and asymmetric addition of carbonyl compounds》 about this compound( cas:75732-01-3 ) in Chemical Science. Keywords: allene carbonyl compound copper catalyst amido cupration asym addition; hydroxyethyl indole preparation enantioselective regioselective. We’ll tell you more about this compound (cas:75732-01-3).
A catalytic enantioselective method for the synthesis of 2-(2-hydroxyethyl)indole scaffolds was developed. The process included catalytic intramol. amido-cupration of an allene to generate a novel allylcopper species, followed by asym. addition of the thus-generated chiral nucleophile to aldehydes and ketones. This was the first example of catalytic indole formation coupled with asym. C-C bond formation via in situ generation of a reactive chiral allylcopper species.
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Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com