Gupta, Aalo K.; Tolman, William B. published the article 《Copper/α-Ketocarboxylate Chemistry With Supporting Peralkylated Diamines: Reactivity of Copper(I) Complexes and Dicopper-Oxygen Intermediates》. Keywords: copper ketocarboxylate peralkylated diamine complex preparation oxygen reactivity; crystal structure copper ketocarboxylate peralkylated diamine complex; oxidative decarboxylation kinetics copper ketocarboxylate peralkylated diamine complex.They researched the compound: Mesitylcopper(I)( cas:75732-01-3 ).Name: Mesitylcopper(I). Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:75732-01-3) here.
To further understand Cu-promoted oxidation reactions, the Cu(I) complexes LCuX (L = N,N’-di-tert-butyl-N,N’-dimethylethylenediamine; X = benzoylformate (BF) or p-nitro-benzoylformate) were synthesized, fully characterized by x-ray crystallog. and spectroscopy in solution, and their reactivity with O2 at -80° examined Oxidative decarboxylation of the α-ketocarboxylate ligand was observed, but only to a significant extent when cyclohexene, cyclooctene, or MeCN was present. Spectroscopic and conductivity data are consistent with mechanistic postulates involving displacement of the α-ketocarboxylate by the additives to a small extent, followed by oxygenation of the LCu(I) moiety to yield Cu-O species that subsequently induce decarboxylation. To test these hypotheses, spectroscopic and kinetic studies of the reactions of Bu4NBF with preformed μ-η2:η2-peroxodicopper(II) and/or bis(μ-oxo)dicopper(III) complexes supported by L or N,N,N’,N’-tetramethylpropylenediamine were performed. In an illustration of a new mode of reactivity for such dicopper-O cores, decarboxylation of the added α-ketocarboxylate was observed and the intermediacy of a carboxylate-bridged μ-η2:η2-peroxodicopper(II) complex was implicated.
As far as I know, this compound(75732-01-3)Name: Mesitylcopper(I) can be applied in many ways, which is helpful for the development of experiments. Therefore many people are doing relevant researches.
Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com