Imamoto, Tsuneo published the artcileCarbon-carbon bond-forming reactions using cerium metal or organocerium(III) reagents, HPLC of Formula: 31253-08-4, the publication is Journal of Organic Chemistry (1984), 49(21), 3904-12, database is CAplus.
Cerium amalgam is an effective reagent for the chemoselective preparation of homoallylic alcs. from allyl halides and carbonyl compounds and for the Reformatskii-type reaction of α-halo esters with carbonyl compounds Organocerium(III) reagents were conveniently generated by the reaction of organolithiums with CeI3 or CeCl3 and they react cleanly at -78 to -65° with various carbonyl compounds to afford the addition products in high yields. The substrates are susceptible to enolization or metal-halogen exchange with simple organolithiums. The same reagents also react with α,β-unsaturated carbonyl compounds to yield 1,2-addition products in high selectivity.
Journal of Organic Chemistry published new progress about 31253-08-4. 31253-08-4 belongs to iodides-buliding-blocks, auxiliary class Iodide,Ester, name is Ethyl 2-Iodopropionate, and the molecular formula is C5H9IO2, HPLC of Formula: 31253-08-4.
Referemce:
https://en.wikipedia.org/wiki/Iodide,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com