The reaction of an aromatic heterocycle with a proton is called a protonation. One of articles about this theory is 《Efficient oxidation of cycloalkanes with simultaneously increased conversion and selectivity using O2 catalyzed by metalloporphyrins and boosted by Zn(AcO)2: A practical strategy to inhibit the formation of aliphatic diacids》. Authors are Shen, Hai-Min; Wang, Xiong; Ning, Lei; Guo, A-Bing; Deng, Jin-Hui; She, Yuan-Bin.The article about the compound:5,10,15,20-Tetrakis (4-methoxyphenyl)-21H,23H-porphine cobalt (II)cas:28903-71-1,SMILESS:COC1=CC=C(C=C1)C(C2=[N]3[Co+2]4([N-]56)[N-]7C(C(C8=CC=C(C=C8)OC)=C3C=C2)=CC=C7C(C9=CC=C(C=C9)OC)=C%10C=CC%11=[N]4%10)=C5C=CC6=C%11C%12=CC=C(C=C%12)OC).Application of 28903-71-1. Through the article, more information about this compound (cas:28903-71-1) is conveyed.
The direct sources of aliphatic acids in cycloalkanes oxidation were investigated, and a strategy to suppress the formation of aliphatic acids was adopted through enhancing the catalytic transformation of oxidation intermediates cycloalkyl hydroperoxides to cycloalkanols by Zn(II) and delaying the emergence of cycloalkanones. Benefitted from the delayed formation of cycloalkanones and suppressed non-selective thermal decomposition of cycloalkyl hydroperoxides, the conversion of cycloalkanes and selectivity towards cycloalkanols and cycloalkanones were increased simultaneously with satisfying tolerance to both of metalloporphyrins and substrates. For cyclohexane, the selectivity towards KA-oil was increased from 80.1% to 96.9% meanwhile the conversion was increased from 3.83% to 6.53%, a very competitive conversion level with higher selectivity compared with current industrial process.
Here is just a brief introduction to this compound(28903-71-1)Application of 28903-71-1, more information about the compound(5,10,15,20-Tetrakis (4-methoxyphenyl)-21H,23H-porphine cobalt (II)) is in the article, you can click the link below.
Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com