The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Mesitylcopper(I)(SMILESS: [Cu]C1=C(C)C=C(C)C=C1C,cas:75732-01-3) is researched.Application In Synthesis of 2-(3,4-Dihydroquinolin-1(2H)-yl)ethanamine. The article 《Conjugate addition of diorganozincs to α,β-unsaturated ketones catalyzed by a copper(I)-sulfonamide combined system》 in relation to this compound, is published in Tetrahedron Letters. Let’s take a look at the latest research on this compound (cas:75732-01-3).
In the presence of a Cu(I)-N-monosubstituted sulfonamide combined catalyst system, diorganozincs react with α,β-unsaturated ketones, e.g., 2-cycloheptenone, to generate Zn enolates, which may be hydrolyzed giving the β-substituted ketones, e.g., 3-ethylcycloheptanone, or used for further aldol reaction or Pd(0)-catalyzed reaction with allyl acetate leading to the regiospecific α,β-vicinal condensation products.
I hope my short article helps more people learn about this compound(Mesitylcopper(I))Formula: C9H11Cu. Apart from the compound(75732-01-3), you can read my other articles to know other related compounds.
Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com