Author: Jessica.F

Iridium and rhodium-catalyzed C-H activation and formyl arylation of benzaldehydes under chelation-assistance was written by Yang, Xifa;Wang, He;Zhou, Xukai;Li, Xingwei. And the article was included in Organic & Biomolecular Chemistry in 2016.Application of 1204518-02-4 The following contents are mentioned in the article:

Mild and efficient synthesis of benzophenones via Ir(III)- and Rh(III)-catalyzed, directing group-assisted formyl C-H arylation of benzaldehydes was developed using diaryliodonium salts, in which Rh(III) and Ir(III) catalysts exhibited a complementary substrate scope. This study involved multiple reactions and reactants, such as Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4Application of 1204518-02-4).

Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4) belongs to iodide derivatives. The indole subunit is an almost ubiquitous component of biologically active natural products, and its study has been the focus of research for decades.Indole was synthesized in moderate yield via an o-naphthoquinone catalyzed tandem cross-coupling of substituted aniline and benzylamine under aerobic oxidation conditions.Application of 1204518-02-4

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Temporary (P=O) directing group enabled carbazole ortho arylation via palladium catalysis was written by Qi, Zhi-Chao;Lou, Qin-Xin;Niu, Yuan;Yang, Shang-Dong. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2021.Safety of Mesityl(p-tolyl)iodonium trifluoromethanesulfonate The following contents are mentioned in the article:

A palladium-catalyzed, temporary P(O) directing group assisted C-H bond arylation of carbazoles was achieved. The release of the directing group occurred spontaneously in the reaction and the mechanistic studies indicated that acid was essential for N-P bond cleavage. This study involved multiple reactions and reactants, such as Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4Safety of Mesityl(p-tolyl)iodonium trifluoromethanesulfonate).

Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4) belongs to iodide derivatives. Indole could be stereoselectively alkylated with chiral cyclopentyl sulfone reagent. Indole was synthesized in moderate yield via an o-naphthoquinone catalyzed tandem cross-coupling of substituted aniline and benzylamine under aerobic oxidation conditions.Safety of Mesityl(p-tolyl)iodonium trifluoromethanesulfonate

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Direct Arylation of Arene and N-Heteroarenes with Diaryliodonium Salts without the Use of Transition Metal Catalyst was written by Wen, Jun;Zhang, Ruo-Yi;Chen, Shan-Yong;Zhang, Ji;Yu, Xiao-Qi. And the article was included in Journal of Organic Chemistry in 2012.COA of Formula: C19H22F3IO3S The following contents are mentioned in the article:

A novel and simple transition metal-free direct arylation of arene and N-heteroarenes with diaryliodonium salts has been developed. This cross-coupling reaction is promoted only by base and gives the desired products, e.g., I, in moderate to good yields. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3COA of Formula: C19H22F3IO3S).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole is an important structural motif of various drugs, therapeutic leads besides its prevalence in numerous natural products, agrochemicals, perfumery, and dyes. Due to this activity, the indole ring system has become an important component or intermediate in the synthesis of heterocycles.COA of Formula: C19H22F3IO3S

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Diverse Tandem Cyclization Reactions of o-Cyanoanilines and Diaryliodonium Salts with Copper Catalyst for the Construction of Quinazolinimine and Acridine Scaffolds was written by Pang, Xinlong;Chen, Chao;Su, Xiang;Li, Ming;Wen, Lirong. And the article was included in Organic Letters in 2014.Related Products of 139139-80-3 The following contents are mentioned in the article:

Two cyclization modes are realized to produce different nitrogen-containing heterocycles, i.e., quinazolin-4(3H)-imines, e.g., I, and acridines, e.g., II, by assembling o-cyanoanilines and diaryliodonium salts via tandem reaction pathways. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Related Products of 139139-80-3).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole, first isolated in 1866, and it is commonly synthesized from phenylhydrazine and pyruvic acid, although several other procedures have been discovered. In addition to indole, the strain-release chemistry worked for numerous substrates including amines, alcohols, thiols, carboxylic acids, imidazoles, and pyrazoles.Related Products of 139139-80-3

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Solvent free catalytic C-H functionalization was written by Bedford, Robin B.;Mitchell, Charlotte J.;Webster, Ruth L.. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2010.Formula: C17H18F3IO3S The following contents are mentioned in the article:

Solvent-free reaction conditions facilitate a range of aromatic C-H functionalizations that traditionally require acidic or disfavored solvents. These reactions include selective ortho- and meta-arylation of aryl carbamates and anilides and selective halogenation reactions. This study involved multiple reactions and reactants, such as Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4Formula: C17H18F3IO3S).

Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4) belongs to iodide derivatives. Indole, also called Benzopyrrole, a heterocyclic organic compound occurring in some flower oils, such as jasmine and orange blossom, in coal tar, and in fecal matter. They are capable of binding to a variety of receptors with high affinity and thus have applications in a wide range of therapeutic areas.Formula: C17H18F3IO3S

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

tert-Butoxide mediated cascade desulfonylation/arylation/hydrolysis of cyclic sulfonyimines using diaryliodonium salts: synthesis of diaryl ether derivatives bearing a 2-aldehyde group was written by Qian, Xiaofei;Han, Jianwei;Wang, Limin. And the article was included in RSC Advances in 2016.Application of 139139-80-3 The following contents are mentioned in the article:

Cascades of cyclic sulfonylimines mediated by tBuOK with diaryliodonium salts giving the diaryl ethers in good yields were developed. Furthermore, bulky ortho-substituted diaryl ethers with an aldehyde group were obtained easily in comparision with metal-catalyzed protocols. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Application of 139139-80-3).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole is an important structural motif of various drugs, therapeutic leads besides its prevalence in numerous natural products, agrochemicals, perfumery, and dyes. In addition to indole, the strain-release chemistry worked for numerous substrates including amines, alcohols, thiols, carboxylic acids, imidazoles, and pyrazoles.Application of 139139-80-3

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

tert-Butoxide mediated cascade desulfonylation/arylation/hydrolysis of cyclic sulfonyimines using diaryliodonium salts: synthesis of diaryl ether derivatives bearing a 2-aldehyde group was written by Qian, Xiaofei;Han, Jianwei;Wang, Limin. And the article was included in RSC Advances in 2016.Recommanded Product: 1204518-02-4 The following contents are mentioned in the article:

Cascades of cyclic sulfonylimines mediated by tBuOK with diaryliodonium salts giving the diaryl ethers in good yields were developed. Furthermore, bulky ortho-substituted diaryl ethers with an aldehyde group were obtained easily in comparision with metal-catalyzed protocols. This study involved multiple reactions and reactants, such as Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4Recommanded Product: 1204518-02-4).

Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4) belongs to iodide derivatives. Indole is an important structural motif of various drugs, therapeutic leads besides its prevalence in numerous natural products, agrochemicals, perfumery, and dyes. Due to this activity, the indole ring system has become an important component or intermediate in the synthesis of heterocycles.Recommanded Product: 1204518-02-4

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Copper-catalyzed direct oxidation and N-arylation of benzylamines with diaryliodonium salts was written by Liu, Xin;Mao, Dan;Wu, Sheng Ying;Yu, Jian Jun;Hong, Gang;Zhao, Qiao;Wang, Li Min. And the article was included in Science China: Chemistry in 2014.COA of Formula: C19H22F3IO3S The following contents are mentioned in the article:

An efficient synthesis of N-arylated amides is developed via copper(II) triflate-catalyzed direct oxidation of (aryl)methyl amines to primary arylamides by air and subsequent N-arylation by aryliodonium salts. The synthetic methodol. is convenient, practical and ecofriendly. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3COA of Formula: C19H22F3IO3S).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole could be stereoselectively alkylated with chiral cyclopentyl sulfone reagent. It is used in perfumery and in making tryptophan, an essential amino acid, and indoleacetic acid (heteroauxin), a hormone that promotes the development of roots in plant cuttings.COA of Formula: C19H22F3IO3S

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Metal-free synthesis of diaryl sulfones from arylsulfinic acid salts and diaryliodonium salts was written by Umierski, Natalie;Manolikakes, Georg. And the article was included in Organic Letters in 2013.Formula: C19H22F3IO3S The following contents are mentioned in the article:

An efficient, high-yielding, and transition-metal-free synthesis of diaryl sulfones from arylsulfinic acid salts and diaryliodonium salts has been developed. The mild reaction conditions tolerate a range of functional groups, and unsym. diaryliodonium salts show high chemoselectivity. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Formula: C19H22F3IO3S).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole produced by Proteus, Pseudomonas, Escherichia and other species was shown to be a growth promoting factor in Arabidopsis thaliana. Moreover, it is known that it controls biofilm formation. However, the role of indole in the cell has not been fully elucidated.Formula: C19H22F3IO3S

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Iodosyl trifluoromethanesulfonate – an efficient reagent for the single-step preparation of diaryliodonium triflate salts was written by Stang, Peter J.;Zhdankin, Viktor V.;Tykwinski, Rik;Zefirov, N. S.. And the article was included in Tetrahedron Letters in 1991.Electric Literature of C19H22F3IO3S The following contents are mentioned in the article:

Treatment of RSiMe₃ [R = Ph, p-tolyl, 2,4,6-Me₃C₆H₂, p-BrC₆H₄, 4-(4-BrC₆H₄)C₆H₄] with iodosyl triflate gave 57-93% R₂I⁺聽^–OTf. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Electric Literature of C19H22F3IO3S).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole is an important structural motif of various drugs, therapeutic leads besides its prevalence in numerous natural products, agrochemicals, perfumery, and dyes. Moreover, it is known that it controls biofilm formation. However, the role of indole in the cell has not been fully elucidated.Electric Literature of C19H22F3IO3S

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com