Author: Jessica.F

Copper-Catalyzed N-Arylation of Nitroenamines with Diaryliodonium Salts was written by Aradi, Klara;Meszaros, Adam;Toth, Balazs L.;Vincze, Zoltan;Novak, Zoltan. And the article was included in Journal of Organic Chemistry in 2017.Related Products of 1204518-02-4 The following contents are mentioned in the article:

A novel synthetic methodol. was developed for the N-arylation of nitroenamine derivatives utilizing diaryliodonium triflates and copper(I) chloride as a catalyst. The procedure enables the easy aryl transfer from the hypervalent species under mild catalytic conditions with unusual heteroatom preference and high efficiency. This study involved multiple reactions and reactants, such as Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4Related Products of 1204518-02-4).

Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4) belongs to iodide derivatives. Indole, also called Benzopyrrole, a heterocyclic organic compound occurring in some flower oils, such as jasmine and orange blossom, in coal tar, and in fecal matter. In addition to indole, the strain-release chemistry worked for numerous substrates including amines, alcohols, thiols, carboxylic acids, imidazoles, and pyrazoles.Related Products of 1204518-02-4

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Base-Promoted Coupling of Carbon Dioxide, Amines and Diaryliodonium Salts: A Phosgene- and Metal-Free Route to O-Aryl Carbamates was written by Xiong, Wenfang;Qi, Chaorong;Peng, Youbin;Guo, Tianzuo;Zhang, Min;Jiang, Huanfeng. And the article was included in Chemistry – A European Journal in 2015.Name: Bis(2,4,6-trimethylphenyl)iodonium triflate The following contents are mentioned in the article:

A phosgene- and metal-free synthesis of O-aryl carbamates is realized through a three-component coupling of carbon dioxide, amines, and diaryliodonium salts. The reaction only requires a base as the promoter, providing access to a diverse array of O-aryl carbamates in moderate to high yields with excellent chemoselectivity. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Name: Bis(2,4,6-trimethylphenyl)iodonium triflate).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole exists overwhelmingly in the 1H-indole form as do other simple indoles. Indole plays a fundamental role for QS in E. coli, being one of the signal molecules responsible for the transcription of a variety of genes (gabT, and tnaB ASTD). Name: Bis(2,4,6-trimethylphenyl)iodonium triflate

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Cesium Carbonate Promoted Direct Arylation of Hydroxylamines and Oximes with Diaryliodonium Salts was written by Yang, Yang;Wu, Xunshen;Han, Jianwei;Mao, Song;Qian, Xiaofei;Wang, Limin. And the article was included in European Journal of Organic Chemistry in 2014.Recommanded Product: Bis(2,4,6-trimethylphenyl)iodonium triflate The following contents are mentioned in the article:

A transition-metal-free approach for the arylation of hydroxylamines and oximes with diaryliodonium salts was developed. The reaction proceeded smoothly at room temperature in the presence of cesium carbonate. As a result, a wide range of N- and O-arylated hydroxylamines were synthesized in good to excellent yields (45-98 %). This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Recommanded Product: Bis(2,4,6-trimethylphenyl)iodonium triflate).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole is an important structural motif of various drugs, therapeutic leads besides its prevalence in numerous natural products, agrochemicals, perfumery, and dyes.Indole was synthesized in moderate yield via an o-naphthoquinone catalyzed tandem cross-coupling of substituted aniline and benzylamine under aerobic oxidation conditions.Recommanded Product: Bis(2,4,6-trimethylphenyl)iodonium triflate

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Arylation of Lithium Sulfinates with Diaryliodonium Salts: A Direct and Versatile Access to Arylsulfones was written by Umierski, Natalie;Manolikakes, Georg. And the article was included in Organic Letters in 2013.COA of Formula: C19H22F3IO3S The following contents are mentioned in the article:

An efficient, transition-metal-free arylation of lithium sulfinates, which are readily accessible from reactions of organolithium reagents with sulfur dioxide, is described. Based on this method, a practical protocol for the direct transformation of (hetero)arenes and (hetero)aromatic halides into diarylsulfones was developed. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3COA of Formula: C19H22F3IO3S).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. In addition to tryptophan, indigo, and indoleacetic acid, numerous compounds obtainable from plant or animal sources contain the indole molecular structure. Indole plays a fundamental role for QS in E. coli, being one of the signal molecules responsible for the transcription of a variety of genes (gabT, and tnaB ASTD). COA of Formula: C19H22F3IO3S

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Copper-Catalyzed Meta-Selective Arylation of Phenol Derivatives: An Easy Access to m-Aryl Phenols was written by Maraswami, Manikantha;Hirao, Hajime;Loh, Teck-Peng. And the article was included in ACS Catalysis in 2021.Category: iodides-buliding-blocks The following contents are mentioned in the article:

Here, we report a general approach to achieve meta-arylated phenols with a simple and common directing group. This copper-catalyzed protocol proceeds with complete meta-selectivity and tolerates a variety of functional groups in both coupling partners. Computational studies have revealed that the reaction proceeded via a Heck-like pathway. This study involved multiple reactions and reactants, such as Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4Category: iodides-buliding-blocks).

Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4) belongs to iodide derivatives. In addition to tryptophan, indigo, and indoleacetic acid, numerous compounds obtainable from plant or animal sources contain the indole molecular structure. They are capable of binding to a variety of receptors with high affinity and thus have applications in a wide range of therapeutic areas.Category: iodides-buliding-blocks

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Direct Copper-Catalyzed C-3 Arylation of Diphenylphosphine Oxide Indoles was written by Huang, Xiao-Ling;Li, Chong;Wang, Juan;Yang, Shang-Dong. And the article was included in Synthesis in 2022.COA of Formula: C17H18F3IO3S The following contents are mentioned in the article:

A simple and effective method for the C-3 arylation of phosphorus-containing indole compounds I (R = H, Me, OMe, Cl, F; R¹ = H, Me, Cl; R² = H, Me; R³ = H, Me) in the presence of CuI under mild conditions was developed. This reaction provides a reliable method for the modification of ligands. This study involved multiple reactions and reactants, such as Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4COA of Formula: C17H18F3IO3S).

Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4) belongs to iodide derivatives. The indole subunit is an almost ubiquitous component of biologically active natural products, and its study has been the focus of research for decades. In addition to indole, the strain-release chemistry worked for numerous substrates including amines, alcohols, thiols, carboxylic acids, imidazoles, and pyrazoles.COA of Formula: C17H18F3IO3S

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Copper-Catalyzed Electrophilic Arylation of Isatoic Anhydride with Diaryliodonium Salts for Synthesis of N-Phenylated Isatoic Anhydrides was written by Wu, Xi-Xi;He, Yonghui;Zhao, Xiao-Jing;Li, Ganpeng. And the article was included in Asian Journal of Organic Chemistry in 2022.Formula: C19H22F3IO3S The following contents are mentioned in the article:

A copper-catalyzed N-arylation of various isatoic anhydrides with diaryliodonium salts was developed by using inexpensive CuI as the catalyst under mild conditions. The method provided diverse N-phenylated isatoic anhydrides in high yields (up to 97%). The mechanism of the N-arylation reaction was proposed to involve an electrophilic addition process. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Formula: C19H22F3IO3S).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole is an important structural motif of various drugs, therapeutic leads besides its prevalence in numerous natural products, agrochemicals, perfumery, and dyes. They are capable of binding to a variety of receptors with high affinity and thus have applications in a wide range of therapeutic areas.Formula: C19H22F3IO3S

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Copper-Catalyzed Regio- and Stereoselective O-Arylation of Enolates was written by Xu, Ze-Feng;Cai, Chen-Xin;Jiang, Min;Liu, Jin-Tao. And the article was included in Organic Letters in 2014.Electric Literature of C17H18F3IO3S The following contents are mentioned in the article:

Copper-catalyzed O-arylation of enolates with diaryliodonium salts as arylating reagents was realized successfully. As important building blocks, 尾-aryloxy carbonyl compounds were obtained in up to 98% yield under mild conditions, and complete control of O-arylation and Z-stereoselectivity were achieved. The origin of the selectivity was also discussed. This study involved multiple reactions and reactants, such as Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4Electric Literature of C17H18F3IO3S).

Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4) belongs to iodide derivatives. The indole subunit is an almost ubiquitous component of biologically active natural products, and its study has been the focus of research for decades.Indole was synthesized in moderate yield via an o-naphthoquinone catalyzed tandem cross-coupling of substituted aniline and benzylamine under aerobic oxidation conditions.Electric Literature of C17H18F3IO3S

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Enantioselective Copper-Catalyzed Construction of Aryl Pyrroloindolines via an Arylation-Cyclization Cascade was written by Zhu, Shaolin;MacMillan, David W. C.. And the article was included in Journal of the American Chemical Society in 2012.Recommanded Product: 1204518-02-4 The following contents are mentioned in the article:

An enantioselective arylation-cyclization cascade has been accomplished using a combination of diaryliodonium salts and asym. copper catalysis. These mild catalytic conditions provide a new strategy for the enantioselective construction of pyrroloindolines, an important alkaloid structural motif that is commonly found among biol. active natural products. This study involved multiple reactions and reactants, such as Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4Recommanded Product: 1204518-02-4).

Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4) belongs to iodide derivatives. Indole, also called Benzopyrrole, a heterocyclic organic compound occurring in some flower oils, such as jasmine and orange blossom, in coal tar, and in fecal matter. Moreover, it is known that it controls biofilm formation. However, the role of indole in the cell has not been fully elucidated.Recommanded Product: 1204518-02-4

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Copper(I)-catalyzed intermolecular cyanoarylation of alkenes: convenient access to 伪-alkylated arylacetonitriles was written by Chen, Xin-Jie;Gui, Qing-Wen;Yi, Rongnan;Yu, Xianyong;Wu, Zhi-Lin;Huang, Ying;Cao, Zhong;He, Wei-Min. And the article was included in Organic & Biomolecular Chemistry in 2020.Synthetic Route of C19H22F3IO3S The following contents are mentioned in the article:

A novel Cu(I)-catalyzed intermol. cyanoarylation of alkenes with diaryliodonium salts as a radical arylating reagent and tetra-butylammonium cyanide as an electrophilic cyanating reagent was established. A broad range of 伪-alkylated arylacetonitriles were efficiently constructed in good to excellent yields under base- and oxidant-free and mild conditions. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Synthetic Route of C19H22F3IO3S).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole is an important structural motif of various drugs, therapeutic leads besides its prevalence in numerous natural products, agrochemicals, perfumery, and dyes. Indole plays a fundamental role for QS in E. coli, being one of the signal molecules responsible for the transcription of a variety of genes (gabT, and tnaB ASTD). Synthetic Route of C19H22F3IO3S

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com