Category: 75732-01-3

Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: Mesitylcopper(I), is researched, Molecular C9H11Cu, CAS is 75732-01-3, about Oligonuclear Homoleptic Copper(I) Pyrazolates with Multinucleating Ligand Scaffolds: High Structural Diversity in Solid-State and Solution.COA of Formula: C9H11Cu.

The synthesis of three pyrazole-based, potentially binucleating ligands 3,5-bis(R1NMeCH2)-4-R2pyrazole (L1H: R1 = pyridyl-2-methyl-, R2 = Ph; L2H: R1 = 8-quinolyl-, R2 = H; L3H: R1 = 8-quinolyl-, R2 = Ph) is described. Reaction of L1-3H with 1 equiv of mesitylcopper affords oligonuclear homoleptic complexes [CuL]n (1-3). The single crystal x-ray structure of 2 shows a tetranuclear assembly of linear coordinated Cu(I)-centers bridged by pyrazolato ligands that alternate above and below the Cu4 plane, with addnl. weak interactions from some of the ligand side arms. As the single crystal X-ray structure of 3 reveals, Ph substitution at the 4-position of the pyrazolato framework leads to significant structural modification of the Cu4 array, giving a rhombical tetranuclear complex with two linear coordinated Cu(I) centers that exhibit a short intramol. Cu···Cu contact (2.8212(10) Å) and two peripheral Cu(I) centers in a distorted tetrahedral coordination mode. Thus, 3 represents a very rare example of an inorganic pyrazolato cuprate which can also be viewed as a partly rearranged structural isomer of 2. Also, the crystal lattice of 3 shows an extended network of intra- and intermol. π-π stacking interactions between the aromatic rings. In solution, 1-3 each form two types of oligomers a and b that slowly (<1 s-1) equilibrate at room temperature Using Diffusion Ordered Spectroscopy (DOSY) and variable temperature 1H NMR spectroscopy, a and b correspond to a tetrameric and a (planar) trimeric species. Coordination of the pyridyl/quinolyl side arms that is observed in the solid state seems to be only transient in solution Although many compounds look similar to this compound(75732-01-3)COA of Formula: C9H11Cu, numerous studies have shown that this compound(SMILES:[Cu]C1=C(C)C=C(C)C=C1C), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

The reaction of an aromatic heterocycle with a proton is called a protonation. One of articles about this theory is 《Direct catalytic asymmetric intramolecular conjugate addition of thioamide to α,β-unsaturated ester》. Authors are Suzuki, Yuta; Yazaki, Ryo; Kumagai, Naoya; Shibasaki, Masakatsu.The article about the compound:Mesitylcopper(I)cas:75732-01-3,SMILESS:[Cu]C1=C(C)C=C(C)C=C1C).Name: Mesitylcopper(I). Through the article, more information about this compound (cas:75732-01-3) is conveyed.

A direct catalytic asym. intramol. conjugate addition of thioamide to α,β-unsaturated esters is reported. Catalytic generation of a thioamide enolate with a soft Lewis acid/hard Bronsted base cooperative catalyst was the key to the efficient catalysis. A mesitylcopper/(S)-Xyl-P-Phos catalyst exhibited high catalytic performance.

Although many compounds look similar to this compound(75732-01-3)Name: Mesitylcopper(I), numerous studies have shown that this compound(SMILES:[Cu]C1=C(C)C=C(C)C=C1C), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 75732-01-3, is researched, Molecular C9H11Cu, about Synthesis of Copper(I) Complexes with Ketimide and Hydrazide Ligands, the main research direction is copper ketimide hydrazide tetranuclear complex preparation crystal structure.HPLC of Formula: 75732-01-3.

Copper(I) chloride reacted with lithium ketimides to form tetrameric homoleptic copper(I) ketimide complexes, [Cu(N:CR2)]4, where R = t-Bu or Ph. Mesityl copper reacted with excess 1-trimethylsilylmethyl-2,2,-dimethylhydrazine to give the mixed ligand complex (2,4,6-C6Me3H2)Cu4[N(SiMe3)NMe2]3. Single-crystal x-ray crystallog. studies revealed that the three complexes have eight-member ring structures in which the ring has a hinged or butterfly shape. Although an eight-member ring structure is common for copper(I) amido, alkyl, and aryl clusters, the structure of [Cu(N:C-t-Bu2)]4 is unusual because the hinge angle is significantly smaller than is common, resulting in short Cu···Cu contacts compared to related complexes.

Although many compounds look similar to this compound(75732-01-3)HPLC of Formula: 75732-01-3, numerous studies have shown that this compound(SMILES:[Cu]C1=C(C)C=C(C)C=C1C), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Darwich, Walid; Haumesser, Paul-Henri; Santini, Catherine C.; Gaillard, Frederic published an article about the compound: Mesitylcopper(I)( cas:75732-01-3,SMILESS:[Cu]C1=C(C)C=C(C)C=C1C ).Electric Literature of C9H11Cu. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:75732-01-3) through the article.

The metalization of porous silicon (PSi) is generally realized through phys. vapor deposition (PVD) or electrochem. processes using aqueous solutions The former uses a strong vacuum and does not allow for a conformal deposition into the pores. In the latter, the water used as solvent causes oxidation of the silicon during the reduction of the salt precursors. Moreover, as PSi is hydrophobic, the metal penetration into the pores is restricted to the near-surface region. Using a solution of organometallic (OM) precursors in ionic liquid (IL), we have developed an easy and efficient way to fully metalize the pores throughout the several-μm-thick porous Si. This process affords supported metallic nanoparticles characterized by a narrow size distribution. This process is demonstrated for different metals (Pt, Pd, Cu, and Ru) and can probably be extended to other metals. Moreover, as no reducing agent is necessary (the decomposition in an argon atm. at 50°C is fostered by surface silicon hydride groups borne by PSi), the safety and the cost of the process are improved.

Although many compounds look similar to this compound(75732-01-3)Electric Literature of C9H11Cu, numerous studies have shown that this compound(SMILES:[Cu]C1=C(C)C=C(C)C=C1C), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Quality Control of Mesitylcopper(I). The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Mesitylcopper(I), is researched, Molecular C9H11Cu, CAS is 75732-01-3, about Copper(I)-Catalyzed Enantioselective Addition of Enynes to Ketones. Author is Wei, Xiao-Feng; Xie, Xiao-Wei; Shimizu, Yohei; Kanai, Motomu.

A copper(I)-catalyzed enantioselective addition of enynes to ketones was developed. The method allows facile construction of enantiomerically enriched tertiary alcs. using skipped enynes as stable hydrocarbon pronucleophiles. The combination of a soft copper(I)-conjugated Bronsted base catalyst with a chiral diphosphine ligand, (S,S)-Ph-BPE, enabled chemoselective deprotonation of the skipped enynes in the presence of ketones bearing intrinsically more acidic α-protons. The catalytically generated chiral allylcopper species enantio-, diastereo-, regio-, and chemoselectively reacted with ketones, thereby demonstrating excellent substrate generality with functional group tolerance. The skipped enyne moieties of the pronucleophiles were exclusively converted to cis-conjugated enynes, which will eventually allow for further versatile transformations.

Although many compounds look similar to this compound(75732-01-3)Quality Control of Mesitylcopper(I), numerous studies have shown that this compound(SMILES:[Cu]C1=C(C)C=C(C)C=C1C), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Name: Mesitylcopper(I). Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: Mesitylcopper(I), is researched, Molecular C9H11Cu, CAS is 75732-01-3, about A heterometallic alkoxide combining hard and soft Lewis acids (Et3PO)2Ba2Cu4(OtBu)8. Author is Borup, Bjoern; Huffman, John C.; Caulton, Kenneth G..

Reaction of Cu(I) mesityl with [Ba(OtBu)2(tBuOH)2]4 occurs with replacement of all protons by Cu to give an insoluble solid of empirical formula BaCu2(OtBu)4. This reacts with Et3PO to give a soluble product characterized by spectroscopic, combustion anal., and x-ray diffraction as (Et3PO)2Ba2Cu4(OtBu)8, an elongated octahedron (trans Ba2) with OtBu groups doubly bridging eight edges. The phosphine oxide has broken up an apparent polymer by coordination of one Et3PO to each Ba.

Although many compounds look similar to this compound(75732-01-3)Name: Mesitylcopper(I), numerous studies have shown that this compound(SMILES:[Cu]C1=C(C)C=C(C)C=C1C), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 75732-01-3, is researched, Molecular C9H11Cu, about Soluble Zintl Phases A14ZnGe16 (A = K, Rb) Featuring [(η3-Ge4)Zn(η2-Ge4)]6- and [Ge4]4- Clusters and the Isolation of [(MesCu)2(η3,η3-Ge4)]4-: The Missing Link in the Solution Chemistry of Tetrahedral Group 14 Element Zintl Clusters, the main research direction is zinc germanium potassium rubidium Zintl preparation electronic structure; crystal structure zinc potassium rubidium germanide Zintl cluster.Category: iodides-buliding-blocks.

The number of Zintl phases containing polyhedral clusters of tetrel elements that are accessible for chem. reactions of the main-group element clusters is rather limited. The synthesis and structural characterization of two novel ternary intermetallic phases A14ZnGe16 (A = K, Rb) are presented, and their chem. reactivity was studied. The compounds can be rationalized as Zintl phases with 14 alkali metal cations A+ (A = K, Rb), two tetrahedral [Ge4]4- Zintl anions, and one anionic heterometallic [(Ge4)Zn(Ge4)]6- cluster per formula unit. The Zn-Ge cluster comprises two (Ge4) tetrahedra linked by a Zn atom, with one (Ge4) tetrahedron coordinating with a triangular face (η3) and the other one with an edge (η2). [(η3-Ge4)Zn(η2-Ge4)]6- is a new isomer of the [(Ge4)Zn(Ge4)]6- anion in Cs6ZnGe8. The phases dissolve in liquid NH3 and thus represent rare examples of soluble Zintl compounds with deltahedral units of Group 14 element atoms. Compounds with tetrahedral [E4]4- species were previously isolated from solution for E = Si, Sn, and Pb, and the current study provides the missing link for E = Ge. Reaction of an NH3 solution of K14ZnGe16 with MesCu (Mes = 2,4,6-Me3C6H2) in the presence of [18]-crown-6 (1,4,7,10,13,16-hexaoxacyclooctadecane) yielded crystals of [K([18]-crown-6)]2K2[(MesCu)2Ge4](NH3)7.5 with the polyanion [(MesCu)2Ge4]4-. This MesCu-stabilized tetrahedral [Ge4]4- cluster also completes [(MesCu)2Si4-xGex]4- clusters, which were previously isolated from solution for x = 0 and 0.7, as the end member with x = 4. The electronic structures of [(Ge4)Zn(Ge4)]6- and [(MesCu)2Ge4]4- were studied in terms of a MO description and analyses of the electron localization functions. The results are compared with band structure calculations for the A14ZnGe16 phases (A = K, Rb).

Compounds in my other articles are similar to this one(Mesitylcopper(I))Category: iodides-buliding-blocks, you can compare them to see their pros and cons in some ways,such as convenient, effective and so on.

Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences called First incorporation of the tetrahedral [Sn4]4- cluster into a discrete solvate Na4[Sn4]·(NH3)13 from solutions of Na4Sn4 in liquid ammonia, Author is Waibel, Markus; Faessler, Thomas F., which mentions a compound: 75732-01-3, SMILESS is [Cu]C1=C(C)C=C(C)C=C1C, Molecular C9H11Cu, Product Details of 75732-01-3.

Treatment of solutions of Na4Sn4 in liquid NH3 with CuMes (Mes = mesityl) and 18-crown-6 afforded crystals Na4[Sn4]·(NH3)13. The structure features anionic units {Na7[Sn4]2} and sep. Na cations, both fully solvated by NH3 mols.

Compounds in my other articles are similar to this one(Mesitylcopper(I))Product Details of 75732-01-3, you can compare them to see their pros and cons in some ways,such as convenient, effective and so on.

Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Heilmann, Julia B.; Scheibitz, Matthias; Qin, Yang; Sundararaman, Anand; Jaekle, Frieder; Kretz, Tonia; Bolte, Michael; Lerner, Hans-Wolfram; Holthausen, Max C.; Wagner, Matthias researched the compound: Mesitylcopper(I)( cas:75732-01-3 ).Electric Literature of C9H11Cu.They published the article 《A synthetic route to borylene-bridged poly(ferrocenylene)s》 about this compound( cas:75732-01-3 ) in Angewandte Chemie, International Edition. Keywords: review borylene bridged polyferrocenylene preparation. We’ll tell you more about this compound (cas:75732-01-3).

A review on synthesis of soluble ferrocene-containing polymer. Iron chains: The highly soluble, ferrocene-containing polymer [-fc-B(Mes)-]n (fc = Fe(C5H4)2, Mes = mesityl), with an average chain length of about 16 repeat units (n = 16), is readily accessible by a novel polycondensation reaction starting from fc(BBr2)2 and HSiEt3. The polymer contains three-coordinate boron centers, which are well-suited for the promotion of electron delocalization along the polymer chain.

Although many compounds look similar to this compound(75732-01-3)Electric Literature of C9H11Cu, numerous studies have shown that this compound(SMILES:[Cu]C1=C(C)C=C(C)C=C1C), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

In general, if the atoms that make up the ring contain heteroatoms, such rings become heterocycles, and organic compounds containing heterocycles are called heterocyclic compounds. An article called NaRb7(Si4-xGex)2 – Soluble Zintl Phases Containing Heteroatomic Tetrahedral [Si4-xGex]4- Clusters, published in 2013, which mentions a compound: 75732-01-3, Name is Mesitylcopper(I), Molecular C9H11Cu, Computed Properties of C9H11Cu.

The quaternary phases NaRb7(Si4-xGex)2 (x = 1-3) crystallize with an NaRb7Ge8-type structure and contain tetrahedral four-atom clusters that consist of Si and Ge atoms. The quaternary phases possess larger cell volumes with increasing Ge amount The formation of heteroat. [Si4-xGex]4- clusters is indicated by chem. different Si environments, which were analyzed by solid-state 29Si MAS (magic-angle spinning) NMR spectroscopy of a 29Si-enriched NaRb7(Si4-xGex)2 sample with x = 0.5 as well as quantum chem. calculations of the NMR coupling parameters. NaRb7(Si4-xGex)2 represents another rare example of a phase with exclusively tetrahedral clusters that readily dissolves in liquid ammonia. The nature of the heteroat. clusters was further investigated by dissolution of NaRb7(Si4-xGex)2 with x = 2 in liquid ammonia. In the presence of MesCu (Mes = mesityl) and 18-crown-6 as a sequestering agent, crystals with the composition [Rb(18-crown-6)]2Rb2[(MesCu)2(Si4-xGex)](NH3)11 were isolated with x = 2.2(1). [(MesCu)2(Si4-xGex)]4- represents another isomer of a MesCu-stabilized tetrahedral anion and supports the observation that Zintl phases, which contain solely tetrahedranide subunits, represent a new class of soluble Zintl phases.

Although many compounds look similar to this compound(75732-01-3)Computed Properties of C9H11Cu, numerous studies have shown that this compound(SMILES:[Cu]C1=C(C)C=C(C)C=C1C), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com