Category: iodides-buliding-blocks

Chan, Li Yan et al. published their research in Organic Letters in 2013 | CAS: 1204518-02-4

Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4) belongs to iodide derivatives. In addition to tryptophan, indigo, and indoleacetic acid, numerous compounds obtainable from plant or animal sources contain the indole molecular structure. More than 200 indole derivatives have already been marketed as drugs or are under advanced stages of clinical trials.Computed Properties of C17H18F3IO3S

Pd(II)-Catalyzed ortho-Arylation of Aryl Phosphates and Aryl Hydrogen Phosphates with Diaryliodonium Triflates was written by Chan, Li Yan;Cheong, Lilian;Kim, Sunggak. And the article was included in Organic Letters in 2013.Computed Properties of C17H18F3IO3S The following contents are mentioned in the article:

Functionalized biaryl compounds were successfully synthesized using phosphates as the ortho-directing group in the Pd(II)/Pd(IV) catalytic cycle. This study involved multiple reactions and reactants, such as Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4Computed Properties of C17H18F3IO3S).

Mesityl(p-tolyl)iodonium trifluoromethanesulfonate (cas: 1204518-02-4) belongs to iodide derivatives. In addition to tryptophan, indigo, and indoleacetic acid, numerous compounds obtainable from plant or animal sources contain the indole molecular structure. More than 200 indole derivatives have already been marketed as drugs or are under advanced stages of clinical trials.Computed Properties of C17H18F3IO3S

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Zhdankin, V. V. et al. published their research in Science of Synthesis in 2007 | CAS: 139139-80-3

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole exists overwhelmingly in the 1H-indole form as do other simple indoles.Indole was synthesized in moderate yield via an o-naphthoquinone catalyzed tandem cross-coupling of substituted aniline and benzylamine under aerobic oxidation conditions.Related Products of 139139-80-3

Product subclass 1: hypervalent iodoarenes and aryliodonium salts was written by Zhdankin, V. V.. And the article was included in Science of Synthesis in 2007.Related Products of 139139-80-3 The following contents are mentioned in the article:

A review of methods to prepare hypervalent iodoarenes and aryliodonium salts and their applications to organic synthesis. This study involved multiple reactions and reactants, such as Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3Related Products of 139139-80-3).

Bis(2,4,6-trimethylphenyl)iodonium triflate (cas: 139139-80-3) belongs to iodide derivatives. Indole exists overwhelmingly in the 1H-indole form as do other simple indoles.Indole was synthesized in moderate yield via an o-naphthoquinone catalyzed tandem cross-coupling of substituted aniline and benzylamine under aerobic oxidation conditions.Related Products of 139139-80-3

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Dey, Archan et al. published their research in Chemical Communications (Cambridge, United Kingdom) in 2005 | CAS: 21969-05-1

1-Iodo-4-(4-nitrophenoxy)benzene (cas: 21969-05-1) belongs to iodide derivatives. Indole, also called Benzopyrrole, a heterocyclic organic compound occurring in some flower oils, such as jasmine and orange blossom, in coal tar, and in fecal matter. In addition to indole, the strain-release chemistry worked for numerous substrates including amines, alcohols, thiols, carboxylic acids, imidazoles, and pyrazoles.Synthetic Route of C12H8INO3

Correlation between molecular dipole moment and centrosymmetry in some crystalline diphenyl ethers was written by Dey, Archan;Desiraju, Gautam R.. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2005.Synthetic Route of C12H8INO3 The following contents are mentioned in the article:

The presence of a large mol. dipole moment in di-Ph ethers leads unequivocally to a centrosym. crystal structure. This study involved multiple reactions and reactants, such as 1-Iodo-4-(4-nitrophenoxy)benzene (cas: 21969-05-1Synthetic Route of C12H8INO3).

1-Iodo-4-(4-nitrophenoxy)benzene (cas: 21969-05-1) belongs to iodide derivatives. Indole, also called Benzopyrrole, a heterocyclic organic compound occurring in some flower oils, such as jasmine and orange blossom, in coal tar, and in fecal matter. In addition to indole, the strain-release chemistry worked for numerous substrates including amines, alcohols, thiols, carboxylic acids, imidazoles, and pyrazoles.Synthetic Route of C12H8INO3

Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Budyk, Mikhail F.’s team published research in Mendeleev Communications in 24 | CAS: 606-55-3

Mendeleev Communications published new progress about 606-55-3. 606-55-3 belongs to iodides-buliding-blocks, auxiliary class Quinoline,Salt, name is 1-Ethyl-2-methylquinolin-1-ium iodide, and the molecular formula is C12H14IN, Computed Properties of 606-55-3.

Budyk, Mikhail F. published the artcileSelf-quenching and self-sensitization in the photochemistry of a styrylquinoline-merocyanine dyad, Computed Properties of 606-55-3, the publication is Mendeleev Communications (2014), 24(3), 140-142, database is CAplus.

Forster resonance energy transfer from a styrylquinoline moiety to merocyanine results in the quenching of the former and the sensitization of the latter in a novel styrylquinoline-merocyanine dyad and appears in photoluminescence and photoisomerization of the dyad.

Mendeleev Communications published new progress about 606-55-3. 606-55-3 belongs to iodides-buliding-blocks, auxiliary class Quinoline,Salt, name is 1-Ethyl-2-methylquinolin-1-ium iodide, and the molecular formula is C12H14IN, Computed Properties of 606-55-3.

Referemce:
https://en.wikipedia.org/wiki/Iodide,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Pan, Zhangjin’s team published research in Angewandte Chemie, International Edition in 60 | CAS: 638-45-9

Angewandte Chemie, International Edition published new progress about 638-45-9. 638-45-9 belongs to iodides-buliding-blocks, auxiliary class Iodide,Aliphatic hydrocarbon chain, name is 1-Iodohexane, and the molecular formula is C6H13I, Product Details of C6H13I.

Pan, Zhangjin published the artcilePalladium/TY-Phos-Catalyzed Asymmetric Intermolecular α-Arylation of Aldehydes with Aryl Bromides, Product Details of C6H13I, the publication is Angewandte Chemie, International Edition (2021), 60(34), 18542-18546, database is CAplus and MEDLINE.

Herein, an efficient Pd-catalyzed asym. intermol. α-arylation reaction of α-alkyl-α-aryl disubstituted aldehydes with aryl bromides, which provided a rapid access to chiral aldehydes bearing an α-all-carbon quaternary stereocenter in moderate to good yields with good er in most cases was reported. In addition, a pair of enantiomers could be easily prepared with the use of the same ligand by exchanging the aryl groups of aldehyde and aryl bromide.

Angewandte Chemie, International Edition published new progress about 638-45-9. 638-45-9 belongs to iodides-buliding-blocks, auxiliary class Iodide,Aliphatic hydrocarbon chain, name is 1-Iodohexane, and the molecular formula is C6H13I, Product Details of C6H13I.

Referemce:
https://en.wikipedia.org/wiki/Iodide,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Deng, Weili’s team published research in Synthesis in 50 | CAS: 31253-08-4

Synthesis published new progress about 31253-08-4. 31253-08-4 belongs to iodides-buliding-blocks, auxiliary class Iodide,Ester, name is Ethyl 2-Iodopropionate, and the molecular formula is C5H9IO2, HPLC of Formula: 31253-08-4.

Deng, Weili published the artcileIron-Catalyzed Carboiodination of Alkynes, HPLC of Formula: 31253-08-4, the publication is Synthesis (2018), 50(15), 2974-2980, database is CAplus.

An iron-catalyzed carboiodination of alkynes/aliphatic alkenes with alkyl iodides at room temperature was developed to afford vinyl iodides I [R1 = Ac, CO2Et, Ph, etc.; R2 = CH2CN, CF2CO2Et, cyclohexyl, etc.] and secondary alkyl iodides II [R3 = n-hexyl, Bn, 4-FC6H4CH2, CH2CH2Ph; R4 = CF2CF3, CF2CO2Et, FCH(CF3)2] resp. This method could provided synthetically useful vinyl iodides with general alkyl chains, fluoroalkyl group, ester and cyano group. Conjugated alkynes or unconjugated alkynes were both suitable for this transformation. A radical pathway was proposed for the mechanism and acetyl tert-Bu peroxide was selected as the radical initiator. Alkenes could also be applied to this chem. and produce more complex alkyl iodides.

Synthesis published new progress about 31253-08-4. 31253-08-4 belongs to iodides-buliding-blocks, auxiliary class Iodide,Ester, name is Ethyl 2-Iodopropionate, and the molecular formula is C5H9IO2, HPLC of Formula: 31253-08-4.

Referemce:
https://en.wikipedia.org/wiki/Iodide,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Wang, Jia-Wang’s team published research in Nature Communications in 12 | CAS: 638-45-9

Nature Communications published new progress about 638-45-9. 638-45-9 belongs to iodides-buliding-blocks, auxiliary class Iodide,Aliphatic hydrocarbon chain, name is 1-Iodohexane, and the molecular formula is C3H6O2, Product Details of C6H13I.

Wang, Jia-Wang published the artcileCatalytic asymmetric reductive hydroalkylation of enamides and enecarbamates to chiral aliphatic amines, Product Details of C6H13I, the publication is Nature Communications (2021), 12(1), 1313, database is CAplus and MEDLINE.

A mild and general nickel-catalyzed asym. reductive hydroalkylation effectively converted to enamides and enecarbamates into drug-like α-branched chiral amines was reported. This reaction involved the regio- and stereoselective hydrometallation of an enamide or enecarbamate to generated a catalytic amount of enantioenriched alkylnickel intermediate, followed by C-C bond formation via alkyl electrophiles.

Nature Communications published new progress about 638-45-9. 638-45-9 belongs to iodides-buliding-blocks, auxiliary class Iodide,Aliphatic hydrocarbon chain, name is 1-Iodohexane, and the molecular formula is C3H6O2, Product Details of C6H13I.

Referemce:
https://en.wikipedia.org/wiki/Iodide,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Cong, Zhenxing’s team published research in Dyes and Pigments in 162 | CAS: 606-55-3

Dyes and Pigments published new progress about 606-55-3. 606-55-3 belongs to iodides-buliding-blocks, auxiliary class Quinoline,Salt, name is 1-Ethyl-2-methylquinolin-1-ium iodide, and the molecular formula is C12H14IN, HPLC of Formula: 606-55-3.

Cong, Zhenxing published the artcileHighly efficient crystal red fluorescent 1,2-squaraine dyes with excellent biocompatibility and bioimaging, HPLC of Formula: 606-55-3, the publication is Dyes and Pigments (2019), 654-661, database is CAplus.

A new family of asym. 1,2-squaraine dyes (1,2-SQs) were designed and synthesized in high yields. The photophys. anal. presented that these 1,2-SQs showed strong red fluorescence in crystal state but weak fluorescence in solution, suggesting their aggregation-induced emission enhancement (AIEE) properties. Single crystals X-ray diffraction revealed that the intense fluorescence in the crystal state can be attributed to the effects of long alkyl chains or large group substituents in the mols., which efficiently prevented the tight intermol. contact and reduced π-π interactions. The biocompatibility and cell imaging applications of SQ4 were further investigated. The results demonstrated that SMMC-7721 cell can be clearly imaged by SQ4, which inferred SQ4 had excellent biocompatibility and potential value for bioimaging.

Dyes and Pigments published new progress about 606-55-3. 606-55-3 belongs to iodides-buliding-blocks, auxiliary class Quinoline,Salt, name is 1-Ethyl-2-methylquinolin-1-ium iodide, and the molecular formula is C12H14IN, HPLC of Formula: 606-55-3.

Referemce:
https://en.wikipedia.org/wiki/Iodide,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Garcia-Dominguez, Andres’s team published research in Journal of the American Chemical Society in 139 | CAS: 31253-08-4

Journal of the American Chemical Society published new progress about 31253-08-4. 31253-08-4 belongs to iodides-buliding-blocks, auxiliary class Iodide,Ester, name is Ethyl 2-Iodopropionate, and the molecular formula is C5H9IO2, HPLC of Formula: 31253-08-4.

Garcia-Dominguez, Andres published the artcileNickel-Catalyzed Reductive Dicarbofunctionalization of Alkenes, HPLC of Formula: 31253-08-4, the publication is Journal of the American Chemical Society (2017), 139(20), 6835-6838, database is CAplus and MEDLINE.

In the presence of tetrapyridinenickel dichloride and 4,4′-di-tert-butyl-2,2′-bipyridine, functionalized alkenes such as allyl acetate underwent regioselective and diastereoselective three-component addition and dicarbofunctionalization reactions with aryl iodides such as RI [R = 4-t-BuC6H4, Ph, 4-MeC6H4, 4-MeOC6H4, 4-FC6H4, 3-MeOC6H4, 3-MeO2CC6H4, 3-F3CC6H4, 3-BrC6H4, 3,5-(F3C)2C6H3, 4-Br-3-MeOC6H3, 3-Cl-5-MeO2CC6H3] and tertiary alkyl iodides such as t-BuI mediated by the organic reductant tetrakis(dimethylamino)ethylene (TDAE) to yield functionalized aryl alkanes such as t-BuCH2CHRCH2OAc [R = 4-t-BuC6H4, Ph, 4-MeC6H4, 4-MeOC6H4, 4-FC6H4, 3-MeOC6H4, 3-MeO2CC6H4, 3-F3CC6H4, 3-BrC6H4, 3,5-(F3C)2C6H3, 4-Br-3-MeOC6H3, 3-Cl-5-MeO2CC6H3] in 29-92% yields.

Journal of the American Chemical Society published new progress about 31253-08-4. 31253-08-4 belongs to iodides-buliding-blocks, auxiliary class Iodide,Ester, name is Ethyl 2-Iodopropionate, and the molecular formula is C5H9IO2, HPLC of Formula: 31253-08-4.

Referemce:
https://en.wikipedia.org/wiki/Iodide,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Zhu, Ru-Yi’s team published research in Journal of the American Chemical Society in 140 | CAS: 1146615-52-2

Journal of the American Chemical Society published new progress about 1146615-52-2. 1146615-52-2 belongs to iodides-buliding-blocks, auxiliary class Other Aromatic Heterocyclic,Bromide,Iodide, name is 3-Bromo-6-iodo-imidazo[1,2-a]pyridine, and the molecular formula is C3H6O2, Synthetic Route of 1146615-52-2.

Zhu, Ru-Yi published the artcileLigand-Enabled γ-C(sp3)-H Activation of Ketones, Synthetic Route of 1146615-52-2, the publication is Journal of the American Chemical Society (2018), 140(10), 3564-3568, database is CAplus and MEDLINE.

We report the first example of Pd(II)-catalyzed γ-C(sp3)-H activation of ketones directed by a practical 2,2-di-Me aminooxyacetic acid auxiliary. 2-Pyridone ligands are identified to enable C(sp3)-H activation for the first time. A rare six-membered palladacycle intermediate is isolated and characterized to elucidate the reaction mechanism. Both (hetero)arylation and vinylation of γ-C(sp3)-H bonds are demonstrated. Sequential β- and γ-C(sp3)-H (hetero)arylation of muscone showcases the utility of this method for late-stage diversification. A convenient Mn(II)-catalyzed auxiliary removal is also developed to further underscore the practicality of this transformation.

Journal of the American Chemical Society published new progress about 1146615-52-2. 1146615-52-2 belongs to iodides-buliding-blocks, auxiliary class Other Aromatic Heterocyclic,Bromide,Iodide, name is 3-Bromo-6-iodo-imidazo[1,2-a]pyridine, and the molecular formula is C3H6O2, Synthetic Route of 1146615-52-2.

Referemce:
https://en.wikipedia.org/wiki/Iodide,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com