Song, Gui-Ting published the artcileSynthesis of monofluorooxazoles with quaternary C-F centers through photoredox-catalyzed radical addition of methylene-2-oxazolines, Application In Synthesis of 63131-30-6, the main research area is monofluorooxazole quaternary carbon fluorine center preparation; bromo fluoro oxoarylpropionate preparation methylene oxazoline radical addition photocatalyst.
A novel photoredox-catalyzed radical addition of methylene-2-oxazolines I (R = Ph, hexyl, cyclohexyl, thiophen-2-yl, etc.) has been developed under visible light irradiation to synthesize monofluorooxazoles II (R1 = Ph, furan-2-yl, 3-methylphenyl, etc.) with a quaternary carbon center using 2-bromo-2-fluoro-3-oxo-3-phenylpropionates R1C(O)C(F)(Br)C(O)OEt as radical source. This method with a simple protocol, scalability and high yield offers a facile path to get diverse monofluorinated oxazoles II with quaternary C-F centers, which are a class of highly valuable motifs and synthons.
Organic & Biomolecular Chemistry published new progress about Photochemical redox reaction. 63131-30-6 belongs to class iodides-buliding-blocks, name is Ethyl 3-(4-iodophenyl)-3-oxopropanoate, and the molecular formula is C11H11IO3, Application In Synthesis of 63131-30-6.
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com